Goodrem said she would be joined on stage by Brian McFadden while Shannon Noll, Guy Sebastian and Paulini will also appear.
“As a Sydneysider I couldn’t be more thrilled to be part of my home town’s Christmas spectacular. I am so excited to be coming home for Christmas,” Goodrem said.
Carols in the Domain will be hosted by Kate Richie on December 20 with a co-host yet to be announced.
Grant Denyer has also said he intends to be ready to return to a co-hosting role, following his accident in September.